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Macromolecular metal complexes with transition-metal ions: Structure of a polymer and efficiency of complexation

✍ Scribed by V. D. Pautov; E. V. Anufrieva; T. D. Anan’eva; V. B. Lushchik; T. N. Nekrasova; R. Yu. Smyslov

Book ID
110197034
Publisher
SP MAIK Nauka/Interperiodica
Year
2006
Tongue
English
Weight
184 KB
Volume
48
Category
Article
ISSN
0965-545X

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Metal Complexes with Macrocyclic Ligands
Metal Complexes with Macrocyclic Ligands. XI. Ring size effect on the complexation rates with transition metal ions
✍ Alex P. Leugger; Liselotte Hertli; Thomas A. Kaden 📂 Article 📅 1978 🏛 John Wiley and Sons 🌐 German ⚖ 509 KB

## Abstract The 12‐16 membered tetraazamacrocycles **1**‐**6** were synthesized, their protonation constants and complexation kinetics measured at 25° and I = 0.50. The results of __Table 1__ Show that p__K__ is strongly influenced by the ring size whereas p__K__ and p__K__ are relatively insensiti