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Macrocyclic Ferrocenyl-Bisimidazoline Palladacycle Dimers as Highly Active and Enantioselective Catalysts for the Aza-Claisen Rearrangement of (Z)-Configured N-para-Methoxyphenyl Trifluoroacetimidates.

✍ Scribed by Sascha Jautze; Paul Seiler; Rene Peters

Publisher: John Wiley and Sons
Year: 2007
Weight: 29 KB
Volume: 38
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200723053

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Macrocyclic Ferrocenyl–Bisimidazoline Pa

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Scheme 1. The aza-Claisen (Overman) rearrangement. Scheme 2. Synthesis of the C 2 -symmetric ligands 8.

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