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Macrocyclic compounds from benzenedithiols and triazine: Modification of tetrathiacalix[4]arene

✍ Scribed by Ashraful Alam; Miharu Yamaguchi; Tatsuya Yamamoto; Shiduko Nakajo; Satoshi Ogawa; Ryu Sato


Publisher
Journal of Heterocyclic Chemistry
Year
2008
Tongue
English
Weight
551 KB
Volume
45
Category
Article
ISSN
0022-152X

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✦ Synopsis


Abstract

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Synthesis of macrocyclic compounds having benzenedithionate and triazine moieties was achieved by an efficient fragment coupling approach. In the solid state, they adopted 1,3‐alternate conformations. Combination of two pairs of electron rich and electron poor units, and ortho‐ortho and/or ortho‐meta connections of sulfur atoms with aromatic carbons were novel features of the macrocycles.


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