Macrocyclic Chemistry: Current Trends and Future Perspectives

✍ Scribed by K. Gloe

• Publisher: Springer
• Year: 2005
• Tongue: English
• Leaves: 459
• Edition: 1
• Category: Library

✦ Synopsis

Macrocyclic Chemistry: Current Trends and Future Perspectives illustrates essential concepts in this expanding research field covering both basic and applied studies. Written by well-known experts from around the world, the topics of the chapters range from new macrocyclic architectures with different functions and self-assembly processes through to the modeling and dynamics of such systems. The content also reflects on application possibilities in analytical chemistry, separation processes, material preparation and medicine. Thus this book serves as a creative source of research strategies and methodic tools.

Providing an excellent overview of the field, this book will beВ a valuable resource for researchers in industry and academic institutions as well as for teachers of science and graduate students.

This book is devoted to the long-standing tradition of the International Symposia on Macrocyclic Chemistry (ISMC) and published to coincide with the 30^th meeting, Dresden, Germany.

✦ Table of Contents

Cover Page......Page 1
Title Page......Page 3
ISBN 1402033648......Page 4
CONTENTS......Page 5
PREFACE......Page 8
1. Introduction......Page 10
2. Origins of the International Symposium on Macrocyclic Chemistry......Page 11
3. The Izatt-Christensen Award......Page 14
5. 1987 Nobel Prize Awardees......Page 18
7. References......Page 20
1. Introduction......Page 24
2. Template Synthesis of Amide-based Catenanes, Rotaxanes and Knots......Page 27
3. Functionalisation of the Amide-based Catenanes, Rotaxanes and Knots......Page 29
4. Construction of Assemblies of Amide Catenanes, Rotaxanes and Knots......Page 33
5. Conclusions and Outlook......Page 41
6. Acknowledgements......Page 42
7. References......Page 43
2. Template Strategies in the Synthesis of Functional Macrocycle Assemblies......Page 46
3. Self-Assembly in the Synthesis of Functional Macrocycle Assemblies......Page 55
6. References......Page 60
1. Introduction......Page 62
2. Linked Aza Macrocyclic Ligand Systems......Page 63
3. Linked mixed-donor Ring Systems......Page 71
4. Acknowledgements......Page 74
5. References......Page 75
1. Introduction......Page 76
2. Nitrile-Functionalised Pendant arm Derivatives of [9]aneN3......Page 77
3. Amino-Functionalised Pendant arm Derivatives of [9]aneN3......Page 82
5. References......Page 93
2. Recognition of Anions......Page 96
3. Recognition of Cations......Page 98
4. Recognition of Neutral Molecules......Page 103
5. Biological System Models......Page 106
6. Electron-transfer Dyads......Page 110
8. References......Page 111
2. Sensing......Page 114
3. Anion Templated Assembly of Pseudorotaxanes and Rotaxanes......Page 120
6. References......Page 126
2. Anion Binding in Aqueous Media......Page 130
3. Signalling Methods......Page 133
4. Reversible Anion Binding at Lanthanide Centres......Page 134
5. References......Page 144
2. Ditopic Receptors for Separated Ions......Page 146
5 where the central polyamine linker wraps around a Cl- anion which brings the two......Page 147
3. Ditopic Receptors for Associated Ion-Pairs......Page 148
4. Ion-Pair Recognition Using Ditopic Receptor 13......Page 149
7. References......Page 159
1. Introduction......Page 162
3. Guanidiniocarbonylpyrroles......Page 172
4. Macrocyclic Systems......Page 178
7. References......Page 180
1. Introduction......Page 182
2. Azacryptands......Page 184
3. Amidocryptands......Page 190
4. Summary......Page 194
5. References......Page 195
1. Introduction......Page 198
2. Structural Features......Page 199
3. Solution Equilibria......Page 205
5. Acknowledgements......Page 209
6. References......Page 210
2. Combinations of Cyclodextrins with Guests......Page 212
3. Cyclodextrins and Polymers......Page 219
4. Azobenzenes Chemically Bonded to Cyclodextrins......Page 220
6. Acknowledgements......Page 224
7. References......Page 225
1. Introduction......Page 228
2. Synthesis......Page 230
3. Photophysical Properties......Page 232
4. Electrochemical Characterization......Page 236
5. Conclusions......Page 238
6. Experimental Section......Page 239
8. References......Page 242
1. Introduction......Page 244
2. Macrocyclic Systems with Ability for E,Z-isomerization......Page 245
3. Macrocyclic Systems with Ability for [2+2]-Photocycloaddition Reaction......Page 248
4. Macrocyclic Systems whose Photochromism is Based on Electrocyclic Reaction......Page 253
5. Conclusions......Page 258
7. References......Page 259
1. Crown Ethers and Biological Activity......Page 262
2. Biological Look-alikes......Page 264
3. Development of Ionophore Mimetics......Page 265
4. Crown Ethers as Membrane Amphiphiles......Page 266
5. Ion Channel Models......Page 267
6. Conclusions......Page 270
8. References......Page 271
2. Interactions of Cytochrome c with Physiological and Non-physiological Binding Partners......Page 276
4. Design and Synthesis of Tetraphenylporphyrin-based Protein Surface Receptors......Page 278
5. Tetraphenylporphyrin-based Synthetic Receptors for Targeting the Cytochrome c Surface......Page 281
5 binds cytochrome c nine-fold stronger than tetraanionic 12 (coproporphyrin I). These......Page 282
7. References......Page 283
2. Structure of Macrocyclic Complexes - Solution vs. Solid State......Page 286
3. Some Unusual Properties of Crown Ether and Calixarene Complexes......Page 288
4. Thermodynamics / Enthalpic vs. Entropic Contributions......Page 291
5. Van der Waals or Hydrophobic Effects ?......Page 293
6. Acknowledgements......Page 295
7. References and Notes......Page 296
2. On the Role of Calorimetry......Page 300
3. Estimating Solvent Contributions to Host-guest Binding......Page 303
4. Evaluation of Binding Mode Diversity......Page 306
5. Conclusions......Page 309
7. References......Page 310
1. Introduction......Page 312
2. Methods......Page 313
3. Applications......Page 314
4. Conclusions and Outlook......Page 327
5. Acknowledgements......Page 328
6. References......Page 329
1. Introduction......Page 336
2. Methods......Page 337
3. Results......Page 338
6. References......Page 353
1. Introduction......Page 358
2. Synthetic Macrocyclic Ligands......Page 359
3. Naturally Occurring Macrocycles......Page 366
4. References......Page 368
1. Introduction......Page 374
2. The Design of Solvent Extractants for Base Metal Recovery......Page 375
3. Macrocycles in Extractive Metallurgical Research and Development......Page 378
4. “Pseudo-macrocyclic” Systems in Extractive Metallurgy......Page 382
5. Reagents to Transport Metal Salts......Page 385
7. Acknowledgements......Page 387
8. References......Page 388
1. Introduction......Page 392
2. Historical Background......Page 393
3. Generic Advantages of Solvent Extraction......Page 394
4. CSSX Solvent Composition......Page 396
5. Flowsheet Design......Page 400
6. Secondary Waste Generation......Page 402
7. Equipment Design......Page 403
8. Issues Related to Further Development and New Applications of CSSX......Page 404
9. Conclusions......Page 408
10. Acknowledgments......Page 409
11. References......Page 410
1. Introduction......Page 416
2. Chemistry......Page 417
4. Biolocalization Studies......Page 419
5. Redox Chemistry and Therapeutic Mechanism......Page 420
6. Synthesis of Conjugates......Page 421
8. Acknowledgment......Page 430
9. References......Page 431
Appendix: Coloured Figures of Chapters 3, 7, 8, 11, 12, 17, 21, 23, 24......Page 436
3. TOWARDS FUNCTIONAL MACROCYCLES: SELF-ASSEMBLY AND TEMPLATE STRATEGIES......Page 438
7. SENSING, TEMPLATION AND SELF-ASSEMBLY BY MACROCYCLIC LIGAND SYSTEMS......Page 439
8. SIGNALLING REVERSIBLE ANION BINDING IN AQUEOUS MEDIA......Page 440
11. STRUCTURAL ASPECTS OF HALIDES WITH CRYPTANDS......Page 441
12. OXOANION SELECTIVITY WITH PROTONATED AZACRYPTATE HOSTS: THE INFLUENCE OF HYDRATION ON STRUCTURE AND STABILITY......Page 443
17. RECOGNITION OF CYTOCHROME c BY TETRAPHENYLPORPHYRIN-BASED PROTEIN SURFACE RECEPTORS......Page 445
21. SIMULATIONS OF THE DYNAMICS 18-CROWN-6 AND ITS COMPLEXES: FROM THE GAS PHASE TO AQUEOUS INTERFACES WITH SC-CO2 AND A ROOM-TEMPERATURE IONIC LIQUID......Page 446
23. LIGAND DESIGN FOR BASE METAL RECOVERY......Page 448
24. USE OF MACROCYCLES IN NUCLEAR-WASTE CLEANUP: A REAL-WORLD APPLICATION OF A CALIXCROWN IN CESIUM SEPARATION TECHNOLOGY......Page 449
A......Page 450
C......Page 451
F......Page 453
I......Page 454
K,L,M......Page 455
N,O,P......Page 456
S......Page 457
T......Page 458
U,V,W,X,Y,Z......Page 459

✦ Subjects

Химия и химическая промышленность;Органическая химия;