Macrocycles and Complex Three-Dimensional Structures Comprising Pt(II) Building Blocks
✍ Scribed by Achim Kaiser; Peter Baeuerle
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 8 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
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## Abstract The 1:1 reaction of the diacetyl monoxime‐2‐pyridyl hydrazone HL^1^ (1) and the pyridine‐2‐carboxaldehyde‐2‐imidazoline hydrazone hydrobromide HL^2^ (2) with copper(II) sulfate pentahydrate in methanol affords a series of new sulfate‐bridged dimeric copper(II) complexes, [Cu^II^~2~(HL^1
to the IR data structural proof is provided principally by the I3C-NMR spectrum (in C6D6) which, apart from signals of the phosphane-and cyclopentadienyl-carbon atoms, contains two doublets of doublets at 6=311.41 and 94.14; these are assigned, respectively, to C' and C2 of the vinylidene ligand. In