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Macrocomplexes on the basis of functionalized polyethylene glycols and copolymers of ethylene oxide and propylene oxide: synthesis and catalysis

✍ Scribed by E.A. Karakhanov; Yu.S. Kardasheva; A.L. Maksimov; V.V. Predeina; E.A. Runova; A.M. Utukin

Book ID
103997571
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
406 KB
Volume
107
Category
Article
ISSN
1381-1169

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✦ Synopsis

Water soluble catalysts combining the properties of metal complexes and surfactants on the basis of terminally functionalized polyethylene glycols and block-copolymers of ethylene oxide and propylene oxide with various combinations of ethylene and propylene oxide fragments were investigated. Polymers, functionalized by dipyridyl and acetylacetone were used as ligands for preparation of Fe(III) and Co(II) complexes, which showed a high activity and selectivity in oxidation of cyclohexane and ethylbenzene by both hydrogen peroxide and oxygen. An aqueous phase hydroformylation rhodium catalyst was prepared on the basis of polyethylene glycols functionalized by phosphine groups.

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