## Abstract The solubility equilibrium of ε−Zn(OH)~2~ in 02M (K)NO~3~ has been investigated at 25°C with ^65^Zn as tracer. All data could be explained assuming the reaction with log \*Ks~0~ = 11,72 ± 0,02 [25°C 0,2 M(K)NO~3~].
Löslichkeitsprodukte von Metalloxiden und -hydroxiden. 8. Mitteilung. Die Löslichkeit gealterter Eisen(III)-hydroxid-Fällungen
✍ Scribed by P. Schindler; W. Michaelis; W. Feitknecht
- Publisher
- John Wiley and Sons
- Year
- 1963
- Tongue
- German
- Weight
- 338 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0018-019X
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✦ Synopsis
Abstract
The solubility of aged iron(III) hydroxide precipitates was investigated by determining [Fe^3+^] and [H^+^] of solutions in contact with the solid phases. [Fe^3+^] and [H^+^] were measured by the EMF.‐method at the constant ionic strength 3M (Na)C10~4~. The precipitates were investigated by X‐ray and electron microscope methods. The following equilibrium constants were derived:magnified image
📜 SIMILAR VOLUMES
## Abstract From GILBERT & GARETT'S (^2^) data on the solubility of α‐Be(OH)~2~ in diluted acids, the following equilibrium constants have been calculated (25°, ionic strength zero): .
The total solubility of amorphous Fe^III^‐hydroxide and α‐FeOOH in 3M NaClO~4~ has been determined using ^59^Fe as tracer. The solubility determination of the amorphous hydroxide extended over the pH‐range 3–14. At pH < 3.5 the results agree satisfactorily with the value calculated using the solubil
The state of iron(III)‐hydroxide in aqueous solutions of very low concentrations has been investigated using ^59^Fe as tracer. From very dilute solutions (10^−5^ M, 10^−7^ M and 10^−9^ M) brought to a pH between ∼ 5–12 practically all the iron hydroxide can be sedimented by ultracentrifugation. The