𝔖 Bobbio Scriptorium
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Löslichkeitsprodukte von Metalloxiden und -hydroxiden. 8. Mitteilung. Die Löslichkeit gealterter Eisen(III)-hydroxid-Fällungen

✍ Scribed by P. Schindler; W. Michaelis; W. Feitknecht


Publisher
John Wiley and Sons
Year
1963
Tongue
German
Weight
338 KB
Volume
46
Category
Article
ISSN
0018-019X

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✦ Synopsis


Abstract

The solubility of aged iron(III) hydroxide precipitates was investigated by determining [Fe^3+^] and [H^+^] of solutions in contact with the solid phases. [Fe^3+^] and [H^+^] were measured by the EMF.‐method at the constant ionic strength 3M (Na)C10~4~. The precipitates were investigated by X‐ray and electron microscope methods. The following equilibrium constants were derived:magnified image


📜 SIMILAR VOLUMES


Löslichkeitsprodukte von Metalloxiden un
✍ L. Pinto; K. Egger; P. Schindler 📂 Article 📅 1963 🏛 John Wiley and Sons 🌐 German ⚖ 130 KB

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Die Ermittlung der Löslichkeit von Eisen
✍ H. Lengweiler; W. Buser; W. Feitknecht 📂 Article 📅 1961 🏛 John Wiley and Sons 🌐 German ⚖ 686 KB

The total solubility of amorphous Fe^III^‐hydroxide and α‐FeOOH in 3M NaClO~4~ has been determined using ^59^Fe as tracer. The solubility determination of the amorphous hydroxide extended over the pH‐range 3–14. At pH < 3.5 the results agree satisfactorily with the value calculated using the solubil

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✍ H. Lengweiler; W. Buser; W. Feitknecht 📂 Article 📅 1961 🏛 John Wiley and Sons 🌐 German ⚖ 415 KB

The state of iron(III)‐hydroxide in aqueous solutions of very low concentrations has been investigated using ^59^Fe as tracer. From very dilute solutions (10^−5^ M, 10^−7^ M and 10^−9^ M) brought to a pH between ∼ 5–12 practically all the iron hydroxide can be sedimented by ultracentrifugation. The