Ly(α) absorption cross-section of H2O and O2
✍ Scribed by Dieter Kley
- Publisher
- Springer Netherlands
- Year
- 1984
- Tongue
- English
- Weight
- 363 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0167-7764
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✦ Synopsis
The absorption cross-sections of water vapor and oxygen were measured, using a low-pressure radio frequency discharge through traces of hydrogen in argon as a light source for Ly(a) radiation. The cross-sections are OH2 O = 1.59 x 10 -~7 cm 2 and oO2 = 1.13 x 10 -20 + 1.72 x I0 -~ • P, for water and oxygen, respectively, where P is the oxygen pressure in units of Torr. Ly(a) lamps, such as used for this work, are important light sources for photochemical laboratory work and find applications for trace-gas detection in the atmosphere. For the latter application, accurate cross-sections of water vapor and oxygen are needed.
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Laboratory measurements of absolute infrared absorption cross sections for three strong bands of NzOs have been made as a function of temperature from 233 to 350 K. The results of this study confirm most of the recent laboratory studies, indicating reasonable confidence in cross sections for this mo