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Lyotropic numbers of the formate and acetate ions and related thermodynamic properties

✍ Scribed by D. F. C. Morris

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
392 KB
Volume
78
Category
Article
ISSN
0165-0513

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✦ Synopsis

Abstract

The data of Buchner and Kleijn on the flocculation of agar have been employed to calculate the lyotropic numbers of the formate and acetate ions. Hydration heats of the ions, comparable to those of Latimer, Pitzer and Slansky, have been derived from the lyotropic numbers. Other magnitudes, which have been obtained, include lattice energies and standard enthalpies of formation of formates and acetates.

Estimates of the standard enthalpies of formation of the formate and acetate radicals are quoted, and values for the electron affinities of the radicals are given.

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