Luminescent Ruthenium Polypyridyl Complexes Containing Pendant Pyridinium Acceptors
โ Scribed by Berg-Brennan, Christine; Subramanian, P.; Absi, Michelle; Stern, Charlotte; Hupp, Joseph T.
- Book ID
- 126863901
- Publisher
- American Chemical Society
- Year
- 1996
- Tongue
- English
- Weight
- 189 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0020-1669
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๐ SIMILAR VOLUMES
## Abstract **Summary:** An aminoโfunctionalized bipyridine ligand was prepared in order to serve as a bridging unit to an activated lowโmolecularโweight monomethyl ether of poly(ethylene glycol) (PEG). Coordination of a ruthenium(II) phenantroline precursor onto the formed PEGโcontaining bipyridin
The spectroscopic properties of complexes denoted as Ru(tBu2bpy)~(bpy-X) '~ (R~-X) and Os('Bu2bpy)2(bpy-Y)2+ (Os-Y) are reported (bpy is 2~2'-bipyridine and tBn2bpy is 4,4'bis-(tert-butyt)-2,2'-bpy). X and Y are pairs of functional groups containing bases known to be capable of hydrogen bonding; X/Y