Luminescent Property of a Supramolecular Silver(I)-Thiolate Complex Based on Secondary Ag-S Interactions and Hydrogen Bonds

Synthesis, structures, and luminescence

Synthesis, structures, and luminescence properties of ternary supramolecular hydrogen-bonded complexes involving [(o-C6F4)Hg]3, carbazole, and a Lewis base

✍ Charlotte N. Burress; François P. Gabbaï 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 291 KB

## Abstract The interaction of trimeric perfluoro‐__ortho__‐phenylene mercury (1) with carbazole in dichloromethane, THF, and THF/NEt~3~ leads to the crystallization of [1·C~12~H~8~NH] (2), [1·(C~12~H~8~NH·THF)] (3), and [1·(C~12~H~8~NH·NEt~3~)] (4), respectively. Adducts 3 and 4 have been characte