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Luminescent coordination polymer gels based on rigid terpyridyl phosphine and Ag(i)

✍ Scribed by Tan, Xin; Chen, Xue; Zhang, Jianyong; Su, Cheng-Yong

Book ID
120437525
Publisher
Royal Society of Chemistry
Year
2012
Tongue
English
Weight
960 KB
Volume
41
Category
Article
ISSN
1477-9226

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Two new 4d-4f Ln-Ag heterometallic coordination polymers, {[Ln 3 Ag 5 (IN) 10 (H 2 O) 7 ] Á 4(ClO 4 ) Á 4(H 2 O)} n (Ln ¼ Eu (1) and Sm (2), HIN ¼ isonicotinic acid), have been synthesized under hydrothermal conditions by reactions of Ln 2 O 3 , AgNO 3 , HIN and HClO 4 , and characterized by element