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Luminescence tuning of imidazole-based lanthanide(iii) complexes [Ln = Sm, Eu, Gd, Tb, Dy]

✍ Scribed by Yanagi, Katsuya; Kaziki, Toru; Kachi-Terajima, Chihiro; Kitazawa, Takafumi; Hasegawa, Miki


Book ID
111688315
Publisher
Royal Society of Chemistry
Year
2011
Tongue
English
Weight
783 KB
Volume
40
Category
Article
ISSN
1477-9226

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A very convenient synthesis of an 18-membered triaza-macrocyclic ligand bearing one endocyclic terpyridine unit and three acetate pendant groups is reported. This nonadentate ligand forms very stable neutral lanthanide complexes in aqueous solution and efficiently shields the metal ion from the wate