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Luminescence studies of tris(bis(trimethylsilyl)amido)terbium(III) and of its adduct complexes

✍ Scribed by Brittain, Harry G.; Wayda, Andrea L.; Mukerji, Ishita


Book ID
118191423
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
548 KB
Volume
26
Category
Article
ISSN
0020-1669

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New Sm(III) -halo-bis(trimethylsilyl)amido complexes [Sm(-X) {N(SiMe 3 ) 2 } 2 (THF)] 2 (X ϭ Cl, Br) were synthesized and their crystal structures were analyzed. These complexes were used as catalysts for the homopolymerization of -caprolactone and ␦-valerolactone and found to initiate ring-opening