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Luminescence of rhenium(I) complexes with highly sterically hindered .alpha.-diimine ligands

✍ Scribed by Zipp, Arden P.; Sacksteder, LouAnn; Streich, Julie; Cook, Andrew; Demas, J. N.; DeGraff, B. A.


Book ID
127169377
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
583 KB
Volume
32
Category
Article
ISSN
0020-1669

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## Abstract The substitution reactions of [Re(CO)~5~X] (X = Cl, Br) with 2,6‐dihalo‐substituted nitrosobenzene derivatives C~6~H~2~YZ~2~NO (Y = H, Cl, Br; Z = Cl, Br) leads to the formation of dinuclear ΞΌ~2~‐η^2^‐__N__,__O__‐nitrosobenzene‐bridged complexes of the type [{(CO)~3~Re(μ‐X)}~2~ONC~6~H~2