Useful yields are achieved in the regioselective direct coupling of amines, amides, and ketones with m-dinitrobenzene, 1-nitronaphthalene, and 1,3-dinitronaphthalene, through oxidatively activated nucleophilic aromatic substitution for hydrogen promoted by fluoride anions.
β¦ LIBER β¦
Lowering the symmetry of difunctionalized coordination compounds via nucleophilic aromatic substitutions
β Scribed by Dennis J Hurley; Yitzhak Tor
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- French
- Weight
- 81 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
Nuc - Ru II (bpy) 2 Ru II (bpy) 2 Br -N N Br N N Nuc 2 3 a Nuc=SCH 3 3b Nuc=SCH 2 CH(NHBoc)CO 2 H Ru II (bpy) 2 Ru II (bpy) 2 Br Nuc Nuc - Br - TETRAHEDRON LETTERS Tetrahedron Letters 42 (2001) 7217-7220
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