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Low temperature x-ray diffraction study of stage 1 graphite-FeCl3

✍ Scribed by H. Mazurek; G. Ghavamishahidi; G. Dresselhaus; M.S. Dresselhaus

Publisher: Elsevier Science
Year: 1982
Tongue: English
Weight: 403 KB
Volume: 20
Category: Article
ISSN: 0008-6223
DOI: 10.1016/0008-6223(82)90041-0

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✦ Synopsis

The temperature dependence of the (001) X-ray reflections in graphite-Fe& is reported. The c-axis unit cell, I,, shows a large expansion with increasing temperature, associated with a large relative expansion of the Fe-Cl interplanar distances and a smaller expansion of the graphite-intercalant interplanar distances. The expansion of the Fe-Cl interlayer distance in the stage I graphite-FeCI1 compound is in good agreement with that of pristine FeCI%. Within experimental accuracy. no changes in I, were observed in the temperature range where magnetic transitions have-been reported.

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