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Low-Temperature Photolysis of Cyclopentadiene

✍ Scribed by Dr. E. H. Gold; Prof. Dr. D. Ginsburg

Publisher: John Wiley and Sons
Year: 1966
Tongue: English
Weight: 119 KB
Volume: 5
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.196602461

No coin nor oath required. For personal study only.

✦ Synopsis

Dedicated to Professor K . Freudenberg on his 80th birthduy

The photolysis of cyclopentadiene at ca. -1OOC in the presence of ketonic sensitizers is reported [21 to afford the products (I)-(3) in equal proportions. We found that photolysis at -78OC with either acetone or benzophenone as sensitizer [31 yields in addition to (1)-( 3), the compounds (4) and (6), and various polymers of cyclopentadiene.

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