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Low Temperature Photochemistry of the Acetone/2-Propanol System

✍ Scribed by Andreas Henne; Hanns Fischer

Publisher
John Wiley and Sons
Year
1975
Tongue
German
Weight
388 KB
Volume
58
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

During UV.‐irradiation of acetone/2‐propanol mixtures at −70° products of photo‐addition of acetone to intermediate enols are formed. The yields of these products exceed the yield of pinacol, the major room temperature product. At −70° the photoadditions are favoured by the long lifetime of acetone enol (≥ 5000 s).

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