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Low-temperature phase transitions of LiCsSO4: ESR of NH+3 and Cr5+

✍ Scribed by Jiang-Tsu Yu; Shen-Yuan Chou; Shu-Jeu Huang


Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
862 KB
Volume
49
Category
Article
ISSN
0022-3697

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CH 3 NH 3 ) 3 Bi 2 Cl 9 exhibits two phase transitions at T c 1 ‫؍‬ 349 K and T c 2 ‫؍‬ 247 K. The upper transition is probably isomorphous and reveals itself by the anomalous evolution of the lattice parameters. This behavior is explained to be due to increasing thermal motion of the methylammonium