Low-temperature isomerization of n-butane to isobutane
β Scribed by N. R. Bursian; N. K. Volnukhina; G. V. Stavrova; E. I. Zhemchugova
- Publisher
- Springer US
- Year
- 1969
- Tongue
- English
- Weight
- 335 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0009-3092
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The four species in the title were decomposed under VLPP conditions at temperatures in the vicinity of 1100Β°K. Three model transition states were constructed that fit the low-pressure data thus obtained and that also yield If EZSS = AEZSS; 2) &OO = A&oo; 3 ) log Alloo = 16.4 per C-C bond broken. Th
## Abstract Using the relative kinetic method, rate coefficients have been determined for the gasβphase reactions of chlorine atoms with propane, __n__βbutane, and isobutane at total pressure of 100 Torr and the temperature range of 295β469 K. The Cl~2~ photolysis (Ξ» = 420 nm) was used to generate