Low-Frequency Dielectric Response of Polystyrene Latex Dispersions
β Scribed by Marcel Minor; ; Herman P. van Leeuwen; Johannes Lyklema
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 228 KB
- Volume
- 206
- Category
- Article
- ISSN
- 0021-9797
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β¦ Synopsis
The low-frequency permittivity and the conductivity increments of a well-characterized polystyrene sulfate latex with constant surface charge density were measured in KCl electrolyte solutions. The ionic strength was varied in the range 0.4-6 mM. The data could be explained with one absolute surface-conductivity parameter over the complete concentration range. The titratable surface charge density correlates well with the surface conductivity, the ions in the double layer having the bulk mobility. The results are in good agreement with static conductivities of plugs composed of the same particles obtained in a previous study (1). The electrokinetic charge obtained from streaming potentials (1) in that study is significantly lower, confirming the presence of conduction behind the shear plane. In order to interpret the conductivity data, simple analytical expressions have been derived for the frequency-dependent complex conductivity of a dilute dispersion of spherical particles with relatively thin double layers (kappaa >>1, where a is the particle radius and kappa-1 the Debye screening length). The expressions are restricted to binary suspending electrolytes. However, no restrictions on the ion mobilities and ion valencies are made. Our results agree well with the numerical results of the dielectric model of Mangelsdorf and White (2, 3) and reduce to O'Brien's static conductivity results (4) in the limit of low frequencies. Copyright 1998 Academic Press.
π SIMILAR VOLUMES
Low-frequency dielectric behavior of membrane/electrolyte systems was studied with artificial membranes made from thin plastic films and NaCl electrolyte of various concentrations. A low-frequency dielectric dispersion or relaxation, which is associated with membrane pores and membrane permeability,
A polystyrene latex suspended in HCl has been studied by dielectric response and dynamic mobility measurements. The aim was to see if these data, along with previous results from other techniques, could be interpreted in a consistent way within the standard electrokinetic model to yield information
## a capacitive admittance component when measuring on The electrical properties of microporous membranes in 1 mM charged microporous membranes in a four-electrode cell. KCl solution have been in vestigated in the frequency range 1 This paper focuses on the detection of such lateral double mHz to
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