Loss of water during heat treatment of acid leached glass and fused silica capillary columns
✍ Scribed by Venema, A. ;Sukkel, J. T.
- Publisher
- John Wiley and Sons
- Year
- 1985
- Tongue
- English
- Weight
- 327 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0935-6304
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✦ Synopsis
A study was carried out on the effects of acid leaching of capillary column wall materials. Leaching experiments with glass and fused silica were performed under static and dynamic conditions; moreover, the influence of the temperature was investigated. The amount of water released during different temperature programs was measured with a microwave plasma detector. Different leaching conditions and column wall materials cause considerable variations in water production. These results probably explain the disappointing deactivation efficiency obtained for fused silica and dynamically leached soft glass if HMDS is used. Evidence was found for an increase in surface area due to acid leaching.