Regardless of its position within the DNA film, cross-linked daunomycin (DM) is efficiently reduced electrochemically, indicating that the electron transfer exhibits a shallow distance dependence. Upon the introduction of an intervening cytosine-adenine (CA) mismatch, the electrochemical response is
Long-range electronic interactions in androstanediones
✍ Scribed by Leo Klasinc; Ljiljana Paša-Tolić; Dražen Vikić-Topić; Jan V. Knop; Sean P. McGlynn
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 199 KB
- Volume
- 63
- Category
- Article
- ISSN
- 0020-7608
No coin nor oath required. For personal study only.
✦ Synopsis
were used to assess the nature of long-range interactions between 3,16-and 3,17-carbonyl groups in androstanediones. The 13 C-NMR results appear to confirm the proposition that the interactions in androstane-3,16-dione are stronger.
📜 SIMILAR VOLUMES
Quantum chemical calculation on an entire molecule of segments of native DNA was performed in an ab initio scheme with a simulated aqueous solution environment by overlapping dimer approximation and negative factor counting method. The hopping conductivity was worked out by random walk theory and co