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Long-range coefficients for the low-lying electronic states of LiB

✍ Scribed by Claude Pouchan; Michel Rérat


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
432 KB
Volume
257
Category
Article
ISSN
0009-2614

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The spectroscopic constants for the triplet and singlet states of LiB below about 30000 cm-~ are determined using an intemally contracted multireference configuration-interaction approach. The ground state is 311 as found in previous work. Transitions between the 311 state and the (1)3E-, (2)3II, an

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## Relativistic CI calculations on the low-lying states of BiF(O+, 1, 2, O+ (II)) arising from the Q\*P\* configuration are carried out. Comparison calculations of the X-s states without spin-orbit interaction (3Z-, IX+ and 'A) are also presented. These calculations enable the assignment of three