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Long range carbon—carbon coupling in olefins. 4-13C-4-propyl-3-heptene and 1-13C-1-methylcyclohexene

✍ Scribed by James L. Marshall; Denis E. Miller

Publisher
John Wiley and Sons
Year
1974
Tongue
English
Weight
333 KB
Volume
6
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

All ^13^C—^13^C splittings involving the C‐4 carbon of 4‐propyl‐3‐heptene and the C‐1 carbon of 1‐methylcyclohexene were determined from the appropriately labeled (> 90%‐^13^C) derivatives. The observed trends in coupling constants continue to offer additional means of carbon chemical shift assignments and to provide mechanistic information regarding the nature of long range carbon—carbon coupling.

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