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Long path infrared spectroscopic study of the reaction of methylperoxy free radicals with nitric oxide

โœ Scribed by Pate, C. T.; Finlayson, B. J.; Pitts, J. N.

Book ID
127363090
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
563 KB
Volume
96
Category
Article
ISSN
0002-7863

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Kinetics of the addition reaction of met
Kinetics of the addition reaction of methyl radicals with nitric oxide studied by pulse radiolysis combined with infrared diode laser spectroscopy
โœ Jerzy T. Jodkowski; Emil Ratajczak; Alfred Sillesen; Palle Pagsberg ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 584 KB

The reaction CHs+NO (+M) +CH,NO (+M) was initiated by pulse radiolysis of acetone/nitric oxide mixtures and the kinetics of methyl radicals was studied by time-resolved infrared absorption spectroscopy. The rate constant was found to be strongly pressure dependent in the range of p( M ) =6.5-150 mba