Long-Lived Triplet State Charge Separation in Novel Piperidine-Bridged Donor−Acceptor Systems
✍ Scribed by van Dijk, Saskia I.; Groen, Cornelis P.; Hartl, František; Brouwer, Albert M.; Verhoeven, Jan W.
- Book ID
- 126903075
- Publisher
- American Chemical Society
- Year
- 1996
- Tongue
- English
- Weight
- 249 KB
- Volume
- 118
- Category
- Article
- ISSN
- 0002-7863
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📜 SIMILAR VOLUMES
Charge separation in isolated supennolecules, consisting of an aniline or Cmethoxy aniline donor and a cyanonaphthalene acceptor connected by a semirigid bridge, is described in terms of irreversible sequential intramolecular relaxation involving electron transfer from an electronically excited mole
The process of intramolecular charge separation was studied in three nearly identical donor-bridge-acceptor compounds (1-3) under jet-cooled conditions. Each consists of a vinylcyanonaphthalene group as a powerful electron acceptor and an anilino derivative as an electron donor, separated by a rigid