We report the two-photon fluorescence excitation spectrum of poly(pphenylenevinylene) over the energy range 1.1-2.0 eV. The onset for two-photon fluorescence excitation is at 1.3 eV with a strong peak near I.475 eV. The peak locates the energy of the lowest even parity excited singlet at 2.95 eV, so
✦ LIBER ✦
Location of the lowest exciton in C60 single crystal by two-photon excitation spectroscopy
✍ Scribed by M. Muccini; R. Danieli; R. Zamboni; C. Taliani; H. Mohn; W. Müller; H.U. ter Meer
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 371 KB
- Volume
- 245
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Two-photon excitation of C6o single crystal at 4 K shows a sharp band at 1.846 eV which is assigned to the lowest tbrbidden Frenkel singlet exciton of Tlg symmetry. This assignment is supported by the analysis of Herzberg-Teller induced photoluminescence.
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Location of the lowest even parity excit
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C.J. Baker; O.M. Gelsen; D.D.C. Bradley
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1993
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Elsevier Science
🌐
English
⚖ 407 KB