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Localized f-electron antiferromagnetism, heavy fermion behavior and mixed valence in Ce3Au3Sb4, Ce3Pt3Sb4 and related compounds

โœ Scribed by K. Katoh; M. Kasaya


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
208 KB
Volume
186-188
Category
Article
ISSN
0921-4526

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The electronic (350-900 nm), infrared and Raman (700-30 cm-1) spectra of polycrystalline samples of the mixedvalence (Ce3'/Ce4') oxysulรde compound were investigated. The compound is a low-gap semiconductor Ce 4 O 4 S 3 with intervalence transitions in the near-infrared (ca. 850 nm) and visible (ca.