We have studied the resonant multiphoton ionization of hydrogen in a three-photon excitation, one-photon ionization scheme. Superimposed on the ionization process we find a dissociation mechanism which manifests itself in a strong H+ signal. The ratio of H+ to Hi stgnals depends on the vibrational q
Localization of multiphoton ionization/dissociation resonance wave functions in AC fields
โ Scribed by Nimrod Moiseyev
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 141 KB
- Volume
- 63
- Category
- Article
- ISSN
- 0020-7608
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โฆ Synopsis
1995 that the complex scaled photoionizingrphotodissociating resonances are associated with ลฝ square integrable functions only when the time-dependent Hamiltonian is represented . in the velocity or acceleration gauges , it is proved here that in the length gauge a narrow ลฝ . resonance wave function and not a broad one! may diverge exponentially at some period of time but yet decays exponentially in space at some other time. When the exterior scaling method is used and the coordinate is rotated into the complex plane by ลฝ . an angle less than 180ะ the resonance quasi-energy state in the length gauge decays to zero, like a bound state, at any given time. The localization of the resonance quasi-energy ลฝ . ลฝ Floquet states in the length gauge as the laser frequency vanishes i.e., when the field is . varied slowly and can be considered as dc field is proven and found to be consistent w ลฝ .
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Based on a multi-configuration self-consistent field and a nuclear wavepacket calculation, we present the effect of dipole moments on the infrared multiphoton dissociation dynamics of hydrogen cyanide in nonstationary laser fields. Use of a linear dipole moment depresses the dissociation ability of