Influence of quantum energy flow and loc
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David M. Leitner
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Article
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1999
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John Wiley and Sons
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English
โ 373 KB
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Just as collisions between a reactant and its environment affect thermal unimolecular reaction rates, as described by the Lindemann mechanism, energy flow between the reaction mode and other modes of the reactant analogously influences microcanonical rates. Conformational isomerization typically pro