chains of Sr 9/8 TiS 3 and Sr 8/7 TiS 3 contain oligomer units (Oh) n (n β«Ψβ¬ 4, 5) made up of face-sharing TiS 6 octahedra (Oh). Given the (TiS 3 ) chains aligned along the z direction, the only occupied d-block levels of each (TiS 3 ) chain are the most sigma bonding level of each (Oh) n oligomer,
Local Structure and Influence of Bonding on the Phase-Change Behavior of the Chalcogenide Compounds K1-xRbxSb5S8.
β Scribed by M. G. Kanatzidis; et al. et al.
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 12 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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