The =CHI and =CD2 stretching vibrational overtones of H&-CD2 have been studied up to V= 6 and V= 3, respectively. We report their interpretation in terms of a transition from normal to local modes, involving Fermi resonance with the C-C stretching and CHz scissoring vibrations. We discuss the altern
Local mode interpretation of the CH and CD stretching vibrational manifolds of isotopic ethylenes, C2H3D and C2HD3
β Scribed by J.L. Duncan; A.M. Ferguson; S.T. Goodlad
- Book ID
- 108008817
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 834 KB
- Volume
- 49
- Category
- Article
- ISSN
- 1386-1425
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Secondary isotope effects were examined in the loss of methyl from the molecular ions of C,D,OC,H, and CD,CH,OC,H, for ion source processes and collisional activation (CA) processes. In the ion source loss of CH, was slightly favored over loss of CD, , but in CA the CH, loss was favored to a much la
Product distributions for the reactions of CH$ and CDf with methanol, methanol-da, and ethanol studied in a tandemkm CpdOtrOTl resonance mass SpeCtrOmeter are reported. The major reaction pathways may 5c rationalized in terms of 3x1 intermediate species havving a pro&mated ether structure. The react