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LixVO2 (0 < x ≤ 1): A new series of layered oxides

✍ Scribed by K. Vidyasagar; J. Gopalakrishnan

Book ID: 103243095
Publisher: Elsevier Science
Year: 1982
Tongue: English
Weight: 161 KB
Volume: 42
Category: Article
ISSN: 0022-4596
DOI: 10.1016/0022-4596(82)90270-5

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A 5-layer mixed valence oxide, \(\mathrm{BaVO}_{2.8}\), has been synthesized by reducing \(\mathrm{Ba}_{2} \mathrm{~V}_{2} \mathrm{O}_{7}\) in high purity hydrogen gas at \(1350^{\circ} \mathrm{C}\). \(\mathrm{BaVO}_{2.9}\) has been obtained by room temperature oxidation of \(\mathrm{BaVO}_{2.8}\) i