Xanthate-Mediated Living Radical Polymer
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Ryan W. Simms; Thomas P. Davis; Michael F. Cunningham
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Article
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2005
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John Wiley and Sons
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English
β 105 KB
## Abstract **Summary:** The MADIX/RAFT mechanism, employing a xanthate as the reversible chainβtransfer agent, has been shown to facilitate the living radical polymerization of vinyl acetate in miniemulsion. Methyl (ethoxycarbonothioyl)sulfanyl acetate (MESA) successfully mediated the polymerizati