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Living polymerization with reversible chain transfer and reversible deactivation: The case of cyclic esters

✍ Scribed by Stanislaw Penczek; Tadeusz Biela; Andrzej Duda


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
168 KB
Volume
21
Category
Article
ISSN
1022-1336

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Triallylstannyllithium-allyllithium as a
✍ Yasuo Horikawa; Takeshi Takeda; Toshiki Takizawa; Taro Akazawa; Ryota Fujio; Tat 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 435 KB 👁 1 views

The anionic polymerization of 1,3-butadiene using a novel metalloidal anion initiator, triallylstannyllithium (TALi)-allyllithium ( ALi), was studied. The TALi-ALi initiated anionic polymerization of 1,3-butadiene gave the star polymer along with the linear polybutadiene (PBD). The star polymer cons