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Living polymerization of propylene and 1-hexene using bis-Cp type metallocene catalysts

✍ Scribed by Yoshifumi Fukui; Masahide Murata; Kazuo Soga

Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
51 KB
Volume
20
Category
Article
ISSN
1022-1336

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πŸ“œ SIMILAR VOLUMES

Polymerization of ethylene and ethylene/
Polymerization of ethylene and ethylene/1-hexene over Ziegler–Natta/metallocene hybrid catalysts supported on MgCl2 prepared by a recrystallization method
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MgCl 2 for use as a catalyst support was prepared by dissolution in methanol and recrystallization in n-decane, followed by vacuum-drying at 2,000 rpm. The prepared support was modified by treatment with alkylaluminum compounds. The activity profile of ethylene over the supported catalysts persisted

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It is demonstrated that the catalyst system bis(pentamethylcyclopentadienyl)-zirconium dichloride (Me 5 Cp) 2 ZrCl 2 -methylaluminoxane (MAO) is able to produce random copolymers of ethene and 1-hexene. The 1-hexene incorporation in the copolymers is extremely small. Even in the case of a molar rati