Effects of steric crowding of the substituent of carboxylate counteranions on living cationic polymerization of isobutyl vinyl ether (IBVE) were investigated with the use of two series of carboxylic acids with various carbonyl substituents [RCOOH; R ฯญ (aliphatic series) CH 3 CH 2 , (CH 3 ) 2 CH, (CH
โฆ LIBER โฆ
Living cationic polymerization of vinyl ethers with carboxylic acid/tin tetrahalide initiating systems. III. Benzoic acid and related weakly acidic carboxylic acids for the living polymerization of isobutyl vinyl ether
โ Scribed by Tamotsu Hashimoto; Toshitaka Takahashi; Toshiyuki Kodaira
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 155 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0887-624X
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Cationic polymerization of isobutyl vinyl ether (IBVE) with acetic acid (CH 3 COOH)/tin tetrahalide (SnX 4 : X ฯญ Cl, Br, I) initiating systems in toluene solvent at 0ยฐC was investigated, and the reaction conditions for living polymerization of IBVE with the new initiating systems were established. A