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Living cationic polymerization of vinyl ethers in the presence of iodomethyl methyl ether and zinc iodide

✍ Scribed by Soonhong Kwon; Yunsung Lee; Soukil Mah

Publisher
The Korean Fiber Society
Year
2001
Tongue
English
Weight
149 KB
Volume
2
Category
Article
ISSN
1229-9197

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## Abstract **Summary:** Vinyl ether oligomers with reactive end groups were prepared by alkylation of silyl enol ethers during propagation. Silyl enol ethers were added to the cationic polymerization of isobutyl vinyl ether, ethyl vinyl ether and methyl vinyl ether. The polymerizations were carrie

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## Abstract The living cationic random copolymerization of MVE and CEVE to obtain functionalized thermo‐responsive PMVE as precursors for more complex PMVE‐containing polymer structures is reported. The random copolymers P(MVE‐__co__‐CEVE) were synthesized at 0 °C in toluene using the DEE/TMSI/ZnI~