Anionic Polymerizations of 1-Adamantyl M
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Takashi Ishizone; Hiroyuki Tajima; Hiroshi Torimae; Seiichi Nakahama
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Article
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2002
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John Wiley and Sons
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English
⚖ 154 KB
## Abstract Anionic polymerizations of 1‐adamantyl methacrylate (**1**) and 3‐methacryloyloxy‐1,1′‐biadamantane (**2**) were carried out in THF at −50 to −78 °C for 24 h. The initiator employed was either [1,1‐bis(4′‐trimethylsilylphenyl)‐3‐methylpentyl]lithium (**3**)/lithium chloride, or diphenyl