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Lithium N-trityl-N-(R)-1-phenethylamide, a readily available and useful base for the enantioselective formation of chiral enolates from achiral ketones

✍ Scribed by Jakub Busch-Petersen; E.J Corey

Publisher: Elsevier Science
Year: 2000
Tongue: French
Weight: 136 KB
Volume: 41
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)01185-0

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✦ Synopsis

Lithium N-trityl-N-(R)-1-phenylethylamide (6) is a readily available and useful reagent for the enantioselective (20:1) conversion of 4-t-butylcyclohexanone to the corresponding (S)-enolate. This reaction provides access to numerous useful chiral compounds.

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ChemInform Abstract: Lithium N-Trityl-N-

ChemInform Abstract: Lithium N-Trityl-N-(R)-1-phenethylamide, a Readily Available and Useful Base for the Enantioselective Formation of Chiral Enolates from Achiral Ketones.

✍ Jakub Busch-Petersen; E. J. Corey 📂 Article 📅 2000 🏛 John Wiley and Sons ⚖ 32 KB 👁 1 views

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