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Lithium Ion Solvation in Room-Temperature Ionic Liquids Involving Bis(trifluoromethanesulfonyl) Imide Anion Studied by Raman Spectroscopy and DFT Calculations

โœ Scribed by Umebayashi, Yasuhiro; Mitsugi, Takushi; Fukuda, Shuhei; Fujimori, Takao; Fujii, Kenta; Kanzaki, Ryo; Takeuchi, Munetaka; Ishiguro, Shin-Ichi


Book ID
120404448
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
136 KB
Volume
111
Category
Article
ISSN
0022-3654

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Conformational structure of room tempera
โœ Takao Fujimori; Kenta Fujii; Ryo Kanzaki; Kazumi Chiba; Hideo Yamamoto; Yasuhiro ๐Ÿ“‚ Article ๐Ÿ“… 2007 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 361 KB

Conformational structure of the N-butyl-N-methyl-pyrrolidinium (P 14 + ) ion within its bis(trifluoromethanesulfonyl) imide (TFSI -) and bromide salts has been studied by means of DFT calculations and Raman spectroscopy. The P 14 + ion gives various types of conformations with respect to the pyrroli