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Lithium complexes and the kinetics of interactions of zinc ions with tetra(N-methyl-4–pyridyl)porphyrins in basic solution

✍ Scribed by M. Quamrul Islam; Peter Hambright

Book ID
110244586
Publisher
Springer
Year
1998
Tongue
English
Weight
142 KB
Volume
23
Category
Article
ISSN
0340-4285

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High-valent oxo-iron(IV) species are commonly proposed as the key intermediates in the catalytic mechanisms of iron enzymes. Water-soluble iron(III) tetrakis-5,10,15,20-(N-methyl-4-pyridyl)porphyrin (Fe(III)TMPyP) has been used as a model of heme-enzyme to catalyse the hydrogen peroxide (H 2 O 2 ) o