Lithium Aluminum Hydride Reactions in Pyridine Solution. IV. Metalation of Di- and Triarylmethanes 1
β Scribed by Lansbury, Peter T.; Thedford, Roosevelt
- Book ID
- 126801646
- Publisher
- American Chemical Society
- Year
- 1962
- Tongue
- English
- Weight
- 640 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
Abdrad-Trialkylborancs react rapidly with lithium aluminium hydride (LAH) in dicthyl ether in the presence of triethykncdiamim (TED) at 0" to form the corresponding lithium triakylborohydrides and aluminum hydride. The aluminum hydride precipitates out of solution as its triethylenediamine adduct. T
The reduction of 3-oxatricyclo[3.2.1.0 2,4 ]octane-endo-6-carbonitrile by lithium aluminum hydride is completed by the formation of exo-2-hydroxy-4-azatricyclo[4.2.1.0 3,7 ]nonane with the structure confirmed (1) by the analysis of 1 H, 13 C, 14 N, and 17 clo[4.2.1.0 3,7 ]nonane prepared by an alter