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Lithium, Aluminum, and Gallium Complexes of the C6F5-Substituted β-Diketiminate Ligand [HC(CMe)2(NC6F5)2]-

✍ Scribed by Dragoslav Vidovic; Jamie N. Jones; Jennifer A. Moore; Alan H. Cowley


Book ID
118286678
Publisher
John Wiley and Sons
Year
2005
Tongue
German
Weight
121 KB
Volume
631
Category
Article
ISSN
0372-7874

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Bis(pentafluorophenyl)cadmium, [Cd(C 6 F 5 ) 2 ], reacts with equimolar amounts of triphenylmethanethiol, TrtSH, in toluene to give [{Cd(C 6 F 5 )(STrt)} 4 ] и 1.5 tol (1). The cuboidal complex of 1 has been transformed into the heterometallic cuboidal complex [{Cd(C 6 F 5 )(STrt)} 3 (OH)K(THF) 3 ]