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Lithiodiphenylmethylisocyanide-(—)-sparteinebis(tetrahydrofuran):Crystal Structure of a Lithiated Isocyanide

✍ Scribed by Dipl.-Chem. Burkhard Ledig; Michael Marsch; Dr. Klaus Harms; Prof. Dr. Gernot Boche


Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
339 KB
Volume
31
Category
Article
ISSN
0044-8249

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Single crystals of the N,N,N',Wtetramethylethylenediamine (TMEDA) complex 6 of the title compound have been isolated. Compound 6 decomposes in the crystalline state above -20'. From the bond lengths and angles obtained by X-ray crystal-structure analysis (data collected at -707, compound 6 is best d