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Lithiation of the dimer of 3-bromo-6-dimethylamino-1-azafulvene. efficacious synthesis of 4-mono- and 4,5-disubstituted pyrrole-2-carboxaldehydes

โœ Scribed by Joseph M Muchowski; Petr Hess


Book ID
103401042
Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
212 KB
Volume
29
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES


Lithiated Azafulvenes by Halogen/Metal I
โœ Brian L. Bray; Petr Hess; Joseph M. Muchowski; Markus E. Scheller ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 244 KB

The first known lithiated 1-azafulvene derivatives were generated by low-temperature halogen/metal interchange, with r-BuLi, from the corresponding brominated 6-diisopropylamino compounds 3b and 12. These Li species reacted with sundry electrophilic reagents to give products which, on basic hydrolys

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The syntheses and mass spectra of 5,6-tetramethylenetetrahydro-l,3-oxazine-2thione and its 4-mono-and 4,4-disubstituted analogs are reported. The primary decay processes under electron impact are loss of the 1,3-oxazine ring, formation of hydrocarbon ions, and rearrangement of the [M -C6H9] + ion.