Lithiation of the dimer of 3-bromo-6-dimethylamino-1-azafulvene. efficacious synthesis of 4-mono- and 4,5-disubstituted pyrrole-2-carboxaldehydes
โ Scribed by Joseph M Muchowski; Petr Hess
- Book ID
- 103401042
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- French
- Weight
- 212 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0040-4039
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๐ SIMILAR VOLUMES
The first known lithiated 1-azafulvene derivatives were generated by low-temperature halogen/metal interchange, with r-BuLi, from the corresponding brominated 6-diisopropylamino compounds 3b and 12. These Li species reacted with sundry electrophilic reagents to give products which, on basic hydrolys
The syntheses and mass spectra of 5,6-tetramethylenetetrahydro-l,3-oxazine-2thione and its 4-mono-and 4,4-disubstituted analogs are reported. The primary decay processes under electron impact are loss of the 1,3-oxazine ring, formation of hydrocarbon ions, and rearrangement of the [M -C6H9] + ion.