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Lithiation of benzothiazolyl substituted epoxides and reactions with electrophiles

✍ Scribed by S. Florio; G. Ingrosso; L. Troisi; V. Lucchini

Publisher: Elsevier Science
Year: 1993
Tongue: French
Weight: 269 KB
Volume: 34
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)91796-9

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✦ Synopsis

Deprotonation of epoxides 1 with n-BuLi or LDA at -90°C produces dark red solulions of oxiranyllithiums 2 which react with electrophiles leading to oxiranes 3.

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