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Lithiation of 3,3-Dimethyl-3-silathiane as a Route to α-Substituted Six-Membered Cyclic Organosilicon Sulfides

✍ Scribed by S. V. Kirpichenko; B. A. Shainyan; E. N. Suslova; A. I. Albanov


Book ID
111545069
Publisher
Springer
Year
2003
Tongue
English
Weight
26 KB
Volume
73
Category
Article
ISSN
1070-3632

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Study of the lithiation of 3-substituted
✍ Cyril Papamicaël; Georges Dupas; Jean Bourguignon; Guy Quéguiner 📂 Article 📅 1994 🏛 Elsevier Science 🌐 French ⚖ 329 KB

The synthesis of new 3-substituted a-carbolines is described and these products were subjected to ortho-lithiation experiments. 3-pivalamido and 3-carboxamido derivatives are cleanly lithiated at 4position. The results are correlated with MNDO calculations. Various 3,4-disubstituted a-carbolines are